Abstract

Abstract The experimental evidence of metamagnetism, giant negative magnetoresistance and spin glass state is presented for the compounds under study. An attempt is made to explain the jump-like phase transition of the colossal negative magnetoresistance of −4433% at 153.2 K into the colossal positive magnetoresistance of +980% at 154.2 K for the spinel sample with selenium. It was emphasized that in all the phenomena described in this paper the double exchange magnetic interaction plays the main role.

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