Metal–organic framework-derived porous metal oxide/graphene nanocomposites as effective adsorbents for mitigating ammonia nitrogen inhibition in high concentration anaerobic digestion of rural organic waste

Abstract

Anaerobic digestion (AD) is an efficient technology that can efficiently convert organic waste into biofuel, but excessive ammonia nitrogen concentration will lead to failure of AD. In this study, a metal–organic framework (MOF)-derived porous metal oxide/graphene nanocomposite (FeMn-MOF/G) was first applied in AD to investigate the mitigation effect of ammonia nitrogen inhibition. Five total solids (TS) concentrations of 8 %, 10 %, 12 %, 15 % and 20 % were set up for AD experiment to investigate the effect of FeMn-MOF/G on AD. The results showed that the average ammonia nitrogen adsorption capacity of FeMn-MOF/G in AD with different TS concentrations was 102.68 mg/g, and the ammonia nitrogen adsorption effect decreased with the increase of TS. When FeMn-MOF/G was added to AD, the ammonia nitrogen concentration of the experimental group could be reduced to 2,086.00 mg/L, and the VFAs concentration was reduced to 1,510.34 mg/L. The methane production in each experimental group increased significantly, and the experimental group MOF-8 obtained the highest cumulative methane production of 321.35 mL/gVS, indicating that FeMn-MOF/G effectively mitigated the ammonia nitrogen inhibition,which promoteed the successful operation of AD. We characterized the prepared FeMn-MOF/G. The results of the vibrating sample magnetometer show that FeMn-MOF/G has excellent superparamagnetic properties. Magnetic recycling is a promising method for the recycling of FeMn-MOF/G materials, which provides a broad prospect for the application of FeMn-MOF/G in AD.