Abstract
New framework solids consisting of coordination polymers [Ce(L)(DMA)(H2O)]n (1), [Nd(L)(DMA)(H2O)]n (2), [Cu2(OH)(L)]n (3) and [Cd2(L)2(4,4′-bipyridyl)]n·(CH3NH2CH3+)2n (4) (H3L = 3,5-(4-carboxybenzyloxy) benzoic acid; DMA = dimethyl acetamide) have been synthesized under hydro(solvo)thermal conditions and characterized by X-ray crystallography. They reveal two-dimensional and three-dimensional network architectures. Thermal analysis (TGA and DTA) features of 1–4 and solid-state variable temperature magnetic susceptibility data of 2 and 3 are reported as well.
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