Metallurgical, surface, and corrosion analysis of Ni–Cr dental casting alloys before and after porcelain firing

Abstract

Objectives A porcelain veneer is often fired on nickel–chromium casting alloys used in dental restorations for aesthetic purposes. The porcelain-fused-to-metal (PFM) process brings the temperature to over 950 °C and may change the alloy's corrosion properties. In this study, the metallurgical, surface, and corrosion properties of two Ni–Cr alloys were examined, before and after PFM firing. Methods Two types of alloy were tested—a high Cr, Mo alloy without Be and a low Cr, Mo alloy with Be. Before the PFM firing, specimens from both alloys were examined for their microstructures, hardness, electrochemical corrosion properties, surface composition, and metal ion release. After the PFM firing, the same specimens were again examined for the same properties. Results Neither of the alloys showed any differences in their electrochemical corrosion properties after the PFM firing. However, both alloys exhibited new phases in their microstructure and significant changes in hardness after firing. In addition, there was a slight increase in CrO x on the surface of the Be-free alloy and increased Mo–Ni was observed on the surface of both alloys via X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). This might be one of the reasons why both alloys had increased Ni and Mo ion release after firing. Significance The PFM firing process changed the alloys’ hardness, microstructure, and surface composition. No significant changes in the alloys’ corrosion behavior were observed, however, the significant increase in metal ion release over a month may need to be further investigated for its clinical effects.