Abstract
The synthesis and characterization of 16 nitrogen α-bonded (tetrazolato)- and (triazolato) indium(III) porphyrin complexes are reported. Each metalloporphyrin was characterized by UV-visible, IR, and 1 H NMR spectroscopy as well as by electrochemistry. The molecular structure of (OEP)In[N 4 C(CH 3 )] was solved and compared to (OEP)In[N 4 C(C 6 H 5 )], whose characterization was reported in a preliminary communication. (OEP)In[N 4 C(CH 3 )] crystallizes in the triclinic system, space group P1
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