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Abstract
Reactions of alkynes with [Cp2Zr(1-butene)(DMAP)] (DMAP = 4-(dimethylamino)pyridine) and chlorophosphines afforded zirconoalkenylphosphines in good to high yields, and their molecular structures were determined by single-crystal X-ray diffraction. The zirconoalkenylphosphines could be transformed into β-functionalized alkenylphosphines through coupling reactions with various electrophiles in the presence of CuCl.
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