Abstract

An incommensurate overlayer structure on a Ga/Si(111) surface, which can be identified with the $6.3\sqrt{3}\ifmmode\times\else\texttimes\fi{}6.3\sqrt{3}R30\ifmmode^\circ\else\textdegree\fi{}$ superstructure observed by the electron diffraction method, has been directly observed using scanning tunneling microscopy. The domain-wall pattern of this structure consists mainly of an array of isolated triangles, in contrast to the meshlike network usually observed on an incommensurate overlayer. A particular feature of this structure is that it assumes a rare domain configuration with $p31m$ symmetry, rather than the $p3m1$ symmetry of the underlying Si(111) double layer, to relax the strain induced by its relatively high Ga coverage.

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