Abstract
A new method for recovering metals from ferritic stainless steel pickling sludge using municipal sludge as a reducing agent is proposed. The effects of temperature, municipal sludge blending ratio, and reaction atmosphere on the recovery characteristics were studied. The migration characteristics of heavy metals (HMs) at different temperatures were also investigated. The results showed that municipal sludge can be used as a reducing agent for metal recovery from pickling sludge. Under optimized conditions (temperature of 650 °C and blending ratio of 5%), the recovery fractions of Fe, Cr, and Ni were 70.1, 53.7, and 60.3%, respectively. The CO2 atmosphere was beneficial for increasing the recovery fraction of the pickling sludge. The migration fractions of Cr, Mn, and Ni were approximately 10%. The migration fractions of Zn, Cu, and Pb, which are semi-volatile HMs, varied significantly with temperature. The migration fractions of Cd and As, which are volatile HMs, could exceed 70%.
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