Abstract
Styrene, 2-methacryloxyethylsulfonic acid and methylenebisacrylamide are copolymerized in the presence of dimethylformamide under γ-irradiation at room temperature to give potentially amphiphilic, microporous resins. The molar fraction of methylenebisacrylamide (the cross-linker) ranges from 1 to 6 mol%. The obtained resins, after grinding and sieving, are treated with solutions of Pd(AcO) 2 and the ion-exchanged polymers are then treated with NaBH 4 in ethanol. The metal content in the materials ranges from 2.1% to 2.4% (w/w). X-ray microprobe analysis shows that Pd(0) is homogeneously dispersed throughout the particles of the polymeric materials. The polymer chain concentration and its distribution in the swollen macromolecular networks are assessed by means of Inverse Steric Exclusion Chromatography (ISEC). In spite of the higher molar proportion of styrene repeating units, the Pd(0)-resin composites swell comparably in water and tetrahydrofurane. Their amphiphilic character is the result of the different swelling properties of the hydrophilic and hydrophobic domains.
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