Metal–organic coordination polymers based on dicarboxylate and a flexible bispyridyl ligand: Synthesis, structures, and photoluminescence

Abstract

Three new transition metal–organic coordination polymers [Zn(bpp)(C 4H 4O 4)]·1.2H 2O 1, [Cd(bpp) 2(H 2O) 2](C 4O 4)·8H 2O 2 and [Cd(bpp) 2(C 4O 4)]·H 2O 3 have been synthesized from the reaction of d 10 block metal, dicarboxylic acid with 1,3-bis(4-pyridyl)-propane (bpp). Structural analysis reveal that the Zn atoms in 1 are bridged by the succinate anions to generate helical chains, which are interlinked by bpp ligands to a 3D framework with Sra (4 2 · 6 3 · 8) topology. The CdN 4O 2 octahedras in 2 are bridged by a pair of bpp ligands to form 1D repeated rhomboid chains, which are assembled into 2D layer via the hydrogen bonds. The six-coordinated Cd 2+ ions in 3 are bridged by the acetylenedicarboxylato ligand to form 1D zigzag chains, which are interconnected by bpp ligands to construct 3D metal–organic framework with a (4 8 · 6 7) topology. The fluorescent spectra of 1– 3 indicate intraligand fluorescence emission upon irradiation.