Metal-organic composite membrane with sub-2 nm pores fabricated via interfacial coordination

Abstract

A metal-organic composite membrane with sub-2 nm pores was developed via interfacial coordination reaction in biphasic systems for the first time. Herein, tannic acid (TA) was dissolved in water, as aqueous phase; iron(III) acetylacetonate (Fe(acac)3), used as Fe(III) source, was dissolved in n-hexane as organic phase. A detailed study was conducted to obtain the defect-free TA-Fe(III) separation layer, including the salt concentration in aqueous solution, pH of the aqueous solution and the ratio of TA to Fe(acac)3. The results indicated that the defect-free TA-Fe(III) composite membrane formed when the tris-complex (TA3-Fe(III)) was achieved. The optimal condition for preparing TA-Fe(III) composite membrane was using aqueous solution containing 0.4 M NaCl at pH = 6 with the ratio of TA to Fe(acac)3 of 10. Different from the typical separation layer formed on the membrane surface by interfacial polymerization, the TA-Fe(III) separation layer was formed in the pores of the substrate, which is attributed to the higher diffusion coefficient of Fe(acac)3 from organic phase to aqueous phase. This work provided a novel strategy to fabricate metal-organic composite membrane with sub-2 nm pores; meanwhile, the new-prepared membrane shows a high Na2SO4 rejection of 97.3% with the water permeance of 8.6 L m−2 h−1 bar−1, and a high VB12 rejection of 97.6%, indicating an excellent ion/molecule separation performance.