Abstract
The X-ray crystal structures of 1 [Cd 2(BAD +) 2(μ-Cl) 4Cl 2] n (BAD + = N3 protonated N 6-benzyladenine)] and 2 [Cd 2(FAD +) 2(μ-Cl) 4Cl 2] n (FAD + = N3 protonated N 6-furfuryladenine) reveal an one-dimensional polymer. In both the structures, the interplay of coordination and hydrogen bonding results in the formation of almost the same type of supramolecular architectures via N–H⋯Cl, C–H⋯Cl and C–H⋯N hydrogen bonds.
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