Metal Mobility in Afforested Sites of an Abandoned Zn-Pb Ore Mining Area

Abstract

Heaps of waste material constitute a serious environmental problem in regions where the historical exploitation and processing of metal ores has taken place. The presented paper describes the trace metal distribution in selected heaps in the lead-zinc mining area of an abandoned mine in Poland, as well as the soil horizons beneath. The study aims at the estimation of the metal remobilization rate in vertical profiles in the spontaneously afforested area in the context of the potential danger it poses to the local groundwater. Individual samples were taken from profiles dug in heaps found in deciduous and coniferous forests. The bulk density, pH, organic matter and carbonate content, as well as the concentration and chemical forms of metals were analysed. Buffer properties and the mineralogical composition were also determined for the selected samples. The investigation indicates excessive cadmium, zinc and lead concentrations in the analysed heap material and the significant secondary enrichment of former soil horizons. A large percentage of these metals occur in potentially mobile forms. It suggests that, despite the high pH of the heap material and the good buffer properties of soil, cadmium and to a lesser extent, zinc, has migrated downwards to depths of at least several dozen centimetres over a period of about 200 years. This is related to soil acidity, particularly in profiles abundant in organic matter resulting from the encroachment of forest communities, particularly of coniferous forest. Spontaneous afforestation forming the litter cover contribute to the stabilization of the heap material and limiting groundwater pollution. Even though specific remediation measures are not needed in this area, it requires long-term monitoring.