Abstract
The interplay of two proximate gallium centres equips the bimetallic complex CyL2Ga2 (1, CyL2 = 1,2-trans-Cy[NC(Me)C(H)C(Me)N(Dip)]2, Dip = 2,6-i-Pr2C6H3) with increased Lewis basicity and higher reducing power compared to the monometallic gallanediyl LGa (2, L = HC[MeCN(Dip)]2) as evidenced by cross-over experiments. Quantum chemical calculations were employed to support the experimental findings.
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