Abstract
Reactions of NaMn(CO) 3 with RuCl 2(PMe 3) 4, RuCl 2(dppm) 2 and RuCl 2(PPh 3) 3 lead either to an ionic species [Ru 2Cl 3(PMe 3) 6]+[Mn(CO) 5] − or to metal—metal bonded RuMn compounds such as RuMn(μ-CO) 2(CO) 3(μ-dppm) 2 Cl, and, quite unexpectedly, to the μ-phosphido complex RuMn(μ-PPh 2)(CO) 6(PPh 3) 2 via a hydride intermediate.
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