Abstract
Partially coordinated meso-tetra(4′-pyridyl)porphyrin, in which two out of four peripheral 4′-(N)py sites are bound to inert RuII complexes, self assembles with cationic square-planar PdII or neutral octahedral RuII 90° angular units to yield a new family of molecular squares, in which the periphery of the porphyrins is rimmed with coordination compounds.
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