Abstract

The combined results of EXAFS and Moessbauer effect spectroscopies have been used to deduce the oxidation state and local structure of iron in iron containing Na, K- and H-chabazites. In the mineral Na,K(Fe) chabazite iron is found to be present as oxo- or hydroxo-bridged Fe(III) oligimers, while in the H-chabazite it is found to be present as Fe(III) ions bridged by oxo- or hydroxo-groups to the zeolite framework. 25 references, 7 figures, 1 table.

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