Abstract

This contribution is concerned with the occurrence of metallic character in K-doped systems and the non-occurrence in Na-doped systems. An N-fold degenerate Hubbard model in the Gutzwiller approximation, previously presented by Jian Ping Lu, is utilized to discuss the metal–insulator transitions observed in these alkali-doped fullerides. The parameters used are derived from INDO calculations in the molecular cluster approach. © 1995 John Wiley & Sons, Inc.

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