Abstract

A transition metal free, efficient, sulfenylation of ketene dithioacetals catalyzed by an HBr–DMSO system is achieved. This strategy employs inexpensive and readily available HBr and DMSO to provide a direct C–H bond sulfenylation with a broad range of aryl thiols. This sulfenylated product is also transformed for the synthesis of pyrazole derivatives in excellent yield.

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