Abstract
The perfluoroalkylsulfonylation (CF3SO2, C2F5SO2 and CHF2SO2) in the enaminone CH bonds has been developed simply via the promotion of molecular iodine by using stable and cheap sodium perfluoroalkyl sulfinates as coupling partners. The stereoselective synthesis of E-configurated α-perfluoroalkylsulfonyl enaminones has been realized via unprecedented CH bond elaboration and CC double bond configuration inversion by free radical process.
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Schedule a callMore From: Chinese chemical letters = Zhongguo hua xue kuai bao
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