Metal-free approach towards efficient synthesis of FDCA using a p-toluene sulfonic acid (p-TSA)-derived heterogeneous solid acid catalyst and oxone over two steps from HMF, fructose and glucose

Abstract

In this work, a metal-free approach towards synthesis of 2,5-furandicarboxylic acid (FDCA) from HMF, fructose and glucose is reported over two steps using p-TSA–POM solid acid catalyst in the first step and oxone as an oxidant in the second step.