Metal fractionation and pollution risk assessment of different sediment sizes in three major southwestern rivers of Caspian Sea

Abstract

To assess the risk of release and percentage of heavy metals in river sediment, nine stations were set up to sample surface sediments from three important rivers situated southwest of the Caspian Sea (the Shafaroud, Karaganroud, and Choubar Rivers). Chemical analyses were conducted on sediment with particle sizes of >38, 63–38, 63–125, 125–250, 250–500 and 500–1000 µm using metal fractionation to determine the degree of risk release and the heavy metal pollution. Common risk indices were used including the cumulative indices of pollution intensity assessment and risk release standards (the modified pollution degree and ecological risk). Generally, when sediment sizes are decreased, the concentration of heavy metals is both larger and greater than the mean concentration of global sediments and earth crust. However, in this research, the concentration of all the metals did not necessarily increase with a decrease in the size of particles. In fact, concentration of cobalt, vanadium, cadmium, and chromium was greater in sediment particle sizes over 63 μm. The results of chemical fractionation analyses indicated that the release risk of metals has two initial phases for: (1) exchangeable bond (F1) and (2) carbonated bond (F2). When compared with other metals, nickel had the greatest tendency to bond within the loose exchangeable phase (F1) across all the stations. Furthermore, with changes in the size of particles, the percentage of heavy metal changes across different bond phases, but will be the greatest in the loose exchangeable phase (F1). This was observed with cobalt, nickel, and chromium at particle sizes larger than 63 μm. The results of ecological risk and modified pollution degree indices indicated that the highest level of pollution was related to sediments with sizes between 63 and 250 μm. Eventually, in order to assess the risk extent of metals present in sediment, a cumulative index referred to as the modified risk assessment code was utilized. It suggested that the greatest risk of toxicity in some stations has been related to particles larger than 63 μm.