Abstract

The reaction of LiBH(C 2H 5) 3 with Os 3(CO) 12 or Ir 4(CO) 12 leads to the formation of spectroscopically detectable formyl complexes. In the latter case, the complex is smoothly converted to [Ir 4(CO) 11H] −, an expected decompositioFn complex of the corresponding polynuclear formyl complex, [Ir 4(CO) 11CHO] −.

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