Abstract
The metal exchange reactions between cadmium meso-triaza-β-tetra-(4-tert-butylbenzo)porphyrinate (Cd-3N(t-BuBz)P) and copper and zinc chlorides in dimethyl sulfoxide were studied by spectrophotometry. The kinetic and energy parameter of the reactions were determined. The results of the metal exchange reaction were compared with those for the reactions of formation Zn-3N(t-BuBz)P and Cu-3N(t-BuBz)P, which were obtained by the interaction of meso-triaza-β-tetra-(4-tert-butylbenzo)porphine (H2-3N(t-BuBz)P) with the corresponding d-metal cations.
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