Abstract
The crystal structure of the title complex, trans-dichloridotetrakis[1-phenyl-3-(1H-1,2,4-triazol-1-yl-κN(4))propan-1-one]copper(II) hexahydrate, [CuCl(2)(C(11)H(11)N(3)O)(4)]·6H(2)O, is isomorphous with that of the corresponding nickel and cobalt compounds. The complex has crystallographic inversion symmetry with the Cu(II) atom on an inversion centre. Each Cu(II) atom is six-coordinated by one N atom from each of the four 1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one ligands in the equatorial plane and by two chloride ligands in axial positions. The structure includes a centrosymmetric irregular up-up-down-down (uudd) water tetramer cluster and O-H...Cl hydrogen bonds. Intermolecular C-H...Cl hydrogen bonds exist between adjacent molecules, resulting in a three-dimensional supramolecular network.
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