Abstract
8-Quinolinyl alkyl ketones, in which the alkyl group has β-hydrogens, react with various RhI and IrI complexes under ethylene to give, in a catalytic process, 8- quinolinyl ethyl ketone; the same reaction with 8-quinolinyl phenyl ketone produces styrene via ethylene insertion into a rhodium–phenyl bond and β-elimination of the resulting phenylethyl complex.
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