Metal carbonyls: new methods of synthesis and investigations

Abstract

Despite the century-long history, the chemistry of metal carbonyls is still developing. However, up to now there has been insufficient progress in the development of new effective synthetic methods for metal carbonyls and their derivatives. This paper reports the results of our studies in the field of development of new methods for synthesizing metal carbonyls and arenemetal tricarbonyls, as well as studies of complexes comprising dichlorides of group IV elements and metal carbonyls, and also application of the compounds considered for olefin hydrosilylation and amine silylation.