Mesoscopic objects, porous layers and nanocomposites—Possibilities of sol–gel chemistry

Abstract

The goal of this study was to prepare mesoscopic objects, thin porous films and nanocomposite coatings with the use of sol–gel technique. Silica nanotubes, titania nanoparticles, porous titania and zirconia coatings as well as titania nanocomposites were successfully synthesized by changing the type of sol–gel precursor, sol composition and applying dip-coating deposition procedure in order to obtain thin films or coatings. All materials were visualized and characterized by the Atomic Force Microcscopy (AFM) technique. Moreover, characterization of titania nanocomposites was extended to the tribological tests performed by means of microtribometer operating in normal loads range of 30–100 mN. The AFM analysis of mesoscopic objects and nanoparticles showed that the diameter of synthesized silica nanotubes was 60–70 nm and the size of titania nanoparticles was 43 nm. In case of porous layers the pore size in titania and zirconia coatings oscillated between 100 and 240 nm, however their shape and distribution were irregular. Microtribological studies of nanocomposites revealed the moderate decrease of the coefficient of friction for samples containing 5, 15 and 5 wt.% of zirconia nanoparticles in titania coatings annealed at 100, 500 and 1000 °C respectively. An enhancement of antiwear properties was already observed for 1 wt.% of nanophase content, except the sample annealed at 500 °C. It was also found that the annealing at high temperatures is a primary factor which affects the reduction of friction and wear of titania coatings while the presence of nanoparticles has secondary effect. Investigations in this study carried out with the use of the AFM technique highlighted the potential and flexibility of sol–gel approach in designing of various types of advanced materials in a form of mesoscopic objects, porous coatings and composite layers. Results collected in this study clearly demonstrated that sol–gel technique can be applied effectively in preparation of broad range of modern materials.