Abstract
Efficient, accurate and reliable detection and monitoring of H2S is of significance in a wide range of areas: industrial production, medical diagnosis, environmental monitoring, and health screening. However the rapid corrosion of commercial platinum-on-carbon (Pt/C) sensing electrodes in the presence of H2S presents a fundamental challenge for fuel cell gas sensors. Herein we report a solution to the issue through the design of a sensing electrode, which is based on Pt supported on mesoporous titanium chromium nitrides (Pt/Ti0.5Cr0.5N). Its desirable characteristics are due to its high electrochemical stability and strong metal-support interactions. The Pt/Ti0.5Cr0.5N-based sensors exhibit a much smaller attenuation (1.3%) in response to H2S than Pt/C-sensor (40%), after 2 months sensing test. Furthermore, the Pt/Ti0.5Cr0.5N-based sensors exhibit negligible cross response to other interfering gases compared with hydrogen sulfide. Results of density functional theory calculation also verify the excellent long-term stability and selectivity of the gas sensor. Our work hence points to a new sensing electrode system that offers a combination of high performance and stability for fuel-cell gas sensors.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
