Mesoporous materials from zeolite seeds as supports for nickel tungsten sulfide active phases: Part 1. Characterization and catalytic properties in hydrocracking reactions

Abstract

MCM-41 aluminosilicate mesostructures (Si/Al = 18) with hexagonal long-range order were assembled from protozeolitic nanoclusters (zeolite seeds) that normally nucleate the crystallization of β-zeolite (BEA). Depending on the duration of the thermal treatment leading to the zeolite seeds, different acidic materials can be obtained. For short pre-treatment duration, the material presents the main characteristics of the MCM-41, whereas for longer pre-treatment duration, there is a gradual transition to a mostly zeolitic one. Hydrocracking of n-decane was carried out on catalysts composed of a sulfided nickel tungsten phase supported on various β-MCM-41 supports as well as on an amorphous silica–alumina and an AlSBA-15 material. The hydrocracking properties of the catalysts are related to the nature of the β-МCМ-41 and vary from the comportment of silica–alumina materials to the one of a zeolite. The nickel-tungsten catalyst supported on β-MCM-6 (6 h pre-treatment for the zeolite seeds solution) is more active and more selective toward isomerization than the catalyst supported on a commercial silica–alumina support.