Mesoporous epoxidized soybean oil-supported copper-based magnetic nanocatalyst and amberlite-supported azide as a green and efficient catalytic system for 1,2,3-triazole synthesis.

Abstract

A new green mesoporous magnetically heterogeneous catalyst was prepared by the copper immobilization onto magnetic epoxidized soybean oil as a nano bio-support and was utilized for the synthesis of 1,4-disubstituted-1,2,3-triazole derivatives in the presence of amberlite supported azide. A great range of triazole derivatives were synthesized from benzyl halides or epoxides halides in high yields at the room temperature. The catalyst was characterized by various techniques such as FT-IR, XRD, VSM, FE-SEM, EDX, TEM, BET, TGA, and ICP analysis. This catalytic system can be reused for five times without any significant decrease in the catalytic activity. Fe3O4@SiO-ESBO/CuO nanocatalyst and amberlite supported azide as a green catalytic system has been used for the regioselective synthesis of triazole derivatives in water. A large range of triazole derivatives were synthesized from benzyl halides or epoxides in high yields.