Mesoporous cellulose nanofibers-interlaced PEDOT:PSS hybrids for chemiresistive ammonia detection.

Abstract

Chemiresistive ammonia (NH3) detection at room temperature is highly desired due to the unique merits of easy miniaturization, low cost, and minor energy consumption especially for portable and wearable electronics. In this regard, poly(3,4-ethylenedioxythiophene):polystyrenesulfonate (PEDOT:PSS) has sparked considerable attention due to the benign room-temperature conductivity and environmental stability, but it is undesirably impeded by limited sensitivity and sluggish reaction kinetics. To overcome these, we incorporated cellulose nanofibers (CNF) into PEDOT:PSS via a facile blending. The constituent-optimized composite sensor displayed sensitive (sensitivity of ∼7.46%/ppm in the range of 0.2-3ppm), selective, and stable NH3 sensing at 25°C at 55% RH, with higher response and less baseline drift than pure PEDOT:PSS counterparts. Additionally, the response/recovery times (4.9s/5.2s toward 1ppm NH3) ranked the best cases of conducting polymers based NH3 sensors. The humidity involved more than twofold response enhancement indicated a huge potential in exhaled breath monitoring. Furthermore, we observed an excellent flexible NH3-sensing performance withbending-tolerant features. This work provides an alternative strategy for trace NH3 sensing with low power consumption, superfast reaction, and high sensitivity.