Abstract
Direct methanol fuel cells (DMFCs) proved to be promising alternative for renewable energy resources. There are several factors involved for the hindrance of their commercialization. Herein, the alteration in catalyst's chemistry has been mainly focused to improve the performance of DMFCs. Mesoporous carbon supported bimetallic combinations of Pt with metallic oxides such as, Pt/CeO2-MC, Pt/PrO2-MC, Pt/NdO2-MC, and Pt/SmO2-MC were synthesized and tested as methanol electro-oxidation anode catalysts. These high-surface area anodes were synthesized by impregnation with Pt to form the desired methanol electro-oxidation catalysts. The as-prepared catalysts were characterized using XRD, BET surface area, and EDS. High surface areas of 684–778m2/g were achieved for the CeO2-MC, PrO2-MC, NdO2-MC, and SmO2-MC, which enabled excellent dispersion of the Pt nanoparticles onto their surfaces. The Pt/CeO2-MC catalyst showed the highest activity for methanol electro-oxidation, which is about 3.5% more than that of the commercial Pt-Ru/C (E-TEK) catalyst. In addition, the prepared catalysts showed significant stability and durability.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
