Abstract

A 2-diazenyl substituted 1,3,4-thiadiazole formed complexes with a series of p-alkoxybenzoic acid by intermolecular hydrogen bonding. The complexes were investigated by polarizing optical microscopy and differential scanning calorimetry to understand the resulting mesogenic behaviours. A study of the complex by powder XRD and molecular modelling was further undertaken to locate the position of hydrogen bonding.

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