Abstract

Si(OH)4, NO3, and TCO2 are shown to be distributed asymmetrically in a north/south direction about the equatorial Pacific using data from WEPOCS III and JGOFS EqPac cruises. Equatorial SiOH4 concentrations are shown to be the product of both geochemical and physical interactions with chemical processes, occurring in at least three regions remote from the equatorial Pacific, and physical delivery processes from the equatorial undercurrent (EUC) to the surface layer varying over a range of time scales. The EUC was partitioned into upper and lower portions, the upper providing source water to the central upwelling area and the lower crossing the Pacific without upwelling and thought to reenter the surface along the coast of Peru and to the eastern equatorial upwelling area. The source waters from the North Pacific, the north equatorial countercurrent (NECC) and from the South Pacific, the New Guinea coastal undercurrent (NGCUC) also were partitioned according to source for the upper and lower EUC. Mean concentrations and ranges of nutrients for each source partition were obtained from field data. Current flow and advective data output from a 3-D physical model were used with the field nutrient data to calculate nutrient fluxes into the EUC. Although the inflow of water from the north and south were approximately equal, the stronger asymmetric distribution of Si(OH)4 compared to NO3 resulted in identifying the South Pacific source as only 30% of the total supply of Si(OH)4 to the EUC and the cause of a low Si(OH)4:NO3 condition. These results suggest a coupling between Southern Ocean productivity, equatorial productivity, and the efflux of CO2 to the atmosphere from the equatorial upwelling system.

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