Abstract

The reaction of PhHgOAc with 2-NCH 3NCTPPH ( 2) gave a mercury(II) complex of (phenylato)(2- N-methyl-5,10,15,20-tetraphenyl-21-carbaporphyrinato- N, N′, N″)-mercury(II), [HgPh(2-NCH 3NCTPP); 7]; the coordination sphere around Hg(1) in 7 was a four-coordinate derivative with a seesaw geometry and dipole–dipole (DD) interaction governed the longitudinal relaxation rate for Hg(1)–Ph–H 2,6 protons of 7 in CDCl 3 (0.01 M) at 599.95 MHz.

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