Melt–rock interactions in a veined mantle: pyroxenite–peridotite reaction experiments at 2 GPa

Giulio Borghini,Patrizia Fumagalli,Elisabetta Rampone

doi:10.5194/ejm-34-109-2022

Giulio Borghini, Patrizia Fumagalli + Show 1 more

Open Access

https://doi.org/10.5194/ejm-34-109-2022

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Abstract

Abstract. Interaction between peridotite and pyroxenite-derived melts can significantly modify the mineralogy and chemistry of the upper mantle, enhancing its heterogeneity, by creating re-fertilized peridotites and secondary-type pyroxenites. We experimentally investigated the reaction between a fertile lherzolite and MgO-rich basaltic andesite produced by partial melting of an olivine-free pyroxenite at 2 GPa and 1300–1450 ∘C. The aim was to constrain the rate and style of melt–peridotite reaction mostly as a function of temperature, i.e. assuming variable physical status of the host peridotite. Experiments juxtaposed pyroxenite on a synthesized fertile lherzolite to evaluate the modal and mineral compositional changes in the fertile lherzolite resulting from the reaction with pyroxenite-derived melt. At 1300 and 1350 ∘C, the reaction produces a thin orthopyroxene-rich reaction zone confined between partially molten pyroxenite and modally unmodified subsolidus lherzolite. Chemical changes in minerals of the pyroxenite crystal mush suggest that element diffusion across the pyroxenite–peridotite interface, coupled with orthopyroxene precipitation, plays a role in the reactive crystallization of mantle pyroxenite veins. At 1380 and 1400 ∘C, infiltration of pyroxenite-derived melt significantly modifies the mineralogy and chemistry of the host peridotite by creating orthopyroxene-rich websterites and pyroxene-rich lherzolite. At 1450 ∘C, pyroxenitic melt fluxes into molten peridotite, enhancing peridotite melting and creating a melt-bearing dunite associated with a refractory harzburgite. At a given pressure, bulk compositions of hybrid rocks originating through melt–peridotite interaction are mostly controlled by the chemistry of the reacting melt. Interaction between pyroxenitic melt and peridotite causes XMg[XMg=Mg/(Mg+Fetot)] and XCr[XCr=Cr/(Cr+Al)] decrease and TiO2 increase in pyroxenes and spinel across the pyroxenite–peridotite boundary. Similar chemical gradients in minerals are observed in pyroxenite–peridotite associations from natural mantle sequences. The comparison with mineral chemistry variations derived by reaction experiments potentially represents a petrologic tool to discriminate between low- versus high-temperature melt–peridotite reactions.

Highlights

Melt–peridotite reactions play an important role in the mineralogical and chemical modification of the upper mantle within a considerable range of depth (e.g. Rampone et al, 2020, and reference therein)
We present the results of reaction experiments, at 2 GPa and 1300–1450 ◦C, between lherzolite and partial melts derived from an olivine-free websterite
We investigated the run products by performing backscattered electron (BSE) images and microanalyses using a JEOL JXA-8200 SuperProbe equipped with five wavelengthdispersive spectrometers (WDSs) and one energy dispersive spectrometer (EDS) at the Dipartimento di Scienze della Terra “Ardito Desio”, University of Milan

Summary

Introduction

Melt–peridotite reactions play an important role in the mineralogical and chemical modification of the upper mantle within a considerable range of depth (e.g. Rampone et al, 2020, and reference therein). Melt–peridotite reactions play an important role in the mineralogical and chemical modification of the upper mantle within a considerable range of depth During the adiabatic (or near-adiabatic) upwelling of a heterogeneous mantle, such low-solidus lithologies encounter partial melting at significantly higher pressure than the host peridotite and experience a much higher degree of melting Partial melts produced by pyroxenitic lithologies, significantly different from peridotitederived liquids, are much more reactive with the surrounding peridotite G. Borghini et al.: Melt–rock interactions in a veined mantle al., 2008; Rosenthal et al, 2014). A large variety of melt– peridotite reactions modify significantly the peridotite by forming a wide range of reaction products as a function of pressure (P ), temperature (T ) and melt composition Recent models have proposed that veined mantle resulting from melt–peridotite reactions represents the source of most oceanic basalts Recent models have proposed that veined mantle resulting from melt–peridotite reactions represents the source of most oceanic basalts (e.g. Donnelly et al, 2004; Sobolev et al, 2007; Lambart et al, 2012; Mallik and Dasgupta, 2012)

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