Melt Migration and Interaction in a Dunite Channel System within Oceanic Forearc Mantle: the Yushigou Harzburgite–Dunite Associations, North Qilian Ophiolite (NW China)

Abstract

AbstractHarzburgite–dunite associations in the Yushigou ophiolitic complex (North Qilian suture, NW China) offer insights into melt migration and melt–rock interaction above a subduction zone. Based on detailed petrographic and in situ analyses, we propose a three-stage model to describe the history of melt channel formation in oceanic arc mantle. In the first stage, high-degree melt extraction was followed by widespread infiltration of small-volume melts, which formed the harzburgite that makes up most of the Yushigou complex. The Yushigou harzburgites thus have highly refractory major-element compositions (olivine Fo = 91·1–93·2, spinel Cr# [atomic 100 × Cr/(Cr + Al)] = 55·2–62·9, whole-rock Mg# = 90·5–92·0, Al2O3 = 0·29–0·74 wt%, CaO = 0·35–0·54 wt%, and low Na2O = 0·02–0·05 wt%) but slight enrichment in the light rare earth elements (LREE). In the second stage, high-volume focused melts infiltrated into the mantle wedge and produced two types of dunite, with high-Cr# (mainly 63·1–73·6) versus low-Cr# (23·6–33·7) spinel. In the low-Cr# dunites, spinels have significantly fewer inclusions and lower Fo values (88·7–90·1) in olivine than in the high-Cr# dunite (Fo = 89·9–90·5), together with higher modal abundances of interstitial sulfides. The two groups of dunite show similar extremely low TiO2 (<0·01 wt%) but different igneous clinopyroxene trace-element patterns (ΣLREE/ΣHREE ≈ 1 in low-Cr# dunite versus ΣLREE/ΣHREE >10 in high-Cr# dunite), indicating distinct differences in the infiltrating melts. The low-Cr# dunite is a cumulate from an anhydrous Al- and S-enriched basaltic melt, whereas the high-Cr# dunite was produced by reaction of harzburgite with a carbon-bearing, alkaline hydrous silicate magma. The confluence of these melt migrations finally formed a channelized dunite network, and later magmatic activity was restricted to these channels. Pulsated melt supply after chromite crystallization formed pervasive sieve-textured rims around spinel in both kinds of dunite, but these are rare in the harzburgite. The third stage was marked by fluid-dominated metasomatism recorded by millimeter-scale veined conduits, which contain carbonate (dolomite and magnesite), amphibole, phlogopite and compound crystal assemblages in both kinds of dunite. CH4–N2–graphite-dominated fluid inclusions are widespread in all lithologies, recording the volatiles transported during the last metasomatic event. The Yushigou complex thus provides a detailed example of interaction between multiple batches of melt or fluid and a lithospheric mantle wedge dunitic channel system. The results of this study further suggest that the formation of podiform chromite requires melt participation, and the nature and origins of the melts can be diverse.