Melanite-bearing nepheline syenite fragments and 40Ar/39Ar age of phlogopite megacrysts in conduit breccia from the Poços de Caldas Alkaline Massif (MG/SP), and implications

Abstract

The Pocos de Caldas Alkaline Massif, located in southeast Brazil, is composed of tinguaites, as well as phonolites and nepheline syenites (NeS), together with assorted pyroclastic rocks. The latter constitute deposits within the Vale do Quartel, and show fragments of alkaline rocks (NeS, tinguaites), basaltic and ultramafic volcanics/subvolvanics, sandstones, and quartz-feldspathic rocks from the crystalline basement. NeS fragments with melanite, previously unknown, and cm-sized fragments of phlogopite megacrysts from related conduit breccia were chosen for detailed studies. The NeS fragments are medium-to coarse grained and contain K-feldspar (Or 95-83), secondary albite (Ab 97), altered nepheline, clinopyroxene (diopside, minor hedenbergite) and partially altered, zoned, idiomorphic melanite. These NeS fragments are typically metaluminous, and point to the existence of similar intrusions hidden at depth, an important input to the massif's petrology. The phlogopite megacrysts are compositionally homogeneous, with high Ti, Mg and Al contents; Ba and F are minor components. Two phlogopite aliquots were dated and yielded identical Ar-40/Ar-39 plateau ages of 87.1(+/- 0.5) Ma and 86.6(+/- 0.5) Ma, which represent minimum and maximum values for phlogopite crystallization and breccia emplacement, respectively. Previously obtained ages for the Pocos de Caldas rocks are concentrated in the 75-86 Ma range interval.