Abstract

AbstractWe demonstrate the supramolecular self‐assembly of {porphyrin‐5,10,15,20‐tetrayltetrakis[(benzene‐5,1,3‐triyl)bis (methylene)]}octakis(phosphonic acid) 1 in the presence of melamine and spermine. The morphology of 1 in the presence of melamine and spermine was different, indicated that change in analytes could be used to control nanostructures. UV‐vis and fluorescence spectroscopic methods were employed to investigate aggregation mode. The self‐assembled nanostructure was confirmed by SEM imaging and XRD measurements.

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