Abstract
After my bachelor degree in chemistry with physics and mathematics (in Dutch kandidaatsexamen) at the University of Amsterdam, I chose to study for my master degree (in Dutch doctoraal) a physical chemistry direction [...]
Highlights
Displacive phase transitions were analyzed almost four decades ago with the help of classical theories such as the Landau theory [12] or with microscopic theories using the mean field approximation [13]
Classical theories are adequate for temperatures well outside the phase transition point, deviations or critical behavior from these theories occur near Tc
These phenomena arise from correlated fluctuations of the order parameter and become important when the length of the correlated fluctuations exceeds the range of forces
Summary
Displacive phase transitions were analyzed almost four decades ago with the help of classical theories such as the Landau theory [12] or with microscopic theories using the mean field approximation [13]. The critical behavior of ST near the 105 K phase transition was verified by means of the Fe3+ and Fe3+-VO impurity centers [15]; both are substitutional for Ti4+.
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