Abstract

After my bachelor degree in chemistry with physics and mathematics (in Dutch kandidaatsexamen) at the University of Amsterdam, I chose to study for my master degree (in Dutch doctoraal) a physical chemistry direction [...]

Highlights

  • Displacive phase transitions were analyzed almost four decades ago with the help of classical theories such as the Landau theory [12] or with microscopic theories using the mean field approximation [13]

  • Classical theories are adequate for temperatures well outside the phase transition point, deviations or critical behavior from these theories occur near Tc

  • These phenomena arise from correlated fluctuations of the order parameter and become important when the length of the correlated fluctuations exceeds the range of forces

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Summary

Introduction

Displacive phase transitions were analyzed almost four decades ago with the help of classical theories such as the Landau theory [12] or with microscopic theories using the mean field approximation [13]. The critical behavior of ST near the 105 K phase transition was verified by means of the Fe3+ and Fe3+-VO impurity centers [15]; both are substitutional for Ti4+.

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