Abstract

Megacrysts and polymineralic fragments of extraordinary diversity from a Tertiary monchiquitic dyke of Ubekendt Ejland comprise three groups: (1) Cr-diopside-fassaitic diopside + olivine, Fo 90.5−81.5 + CrAl spinels. (II) Fassaitic salite-ferrisalite + KTi-pargasite-ferropargasite + apatite + AlTi-magnetite, (III) Scapolite + hyalophane + potassium feldspar + nepheline + analcime. By comparison with mineralogy and phase relations in the host rock and experimental data from alkaline rocks the megacrysts are related to a sequence of crystallization from primitive monchiquitic to potassic phonolitic magmas rich in H 2O and CO 2 at 5–11 kb. Group I megacrysts formed at temperatures of 1300-1150°C and group II between ? 1150–⪸800° C and f o 2 < 10 −9 bar at the latter temperature. High P co 2 may have stabilized the scapolite in the more evolved liquid and K-feldspar and nepheline began to crystallize at ca. 800°C possibly together with the ferrisalite.

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