Abstract

The effect of the mechanical treatment of UO 2 (CH 3 COO) 2 .2H 2 O in a planetary ball mill in air or as a suspension in toluene or benzene on its crystal structure and coordination mode has been studied. No significant changes in the crystal structure are observed. IR-spectroscopy results suggest that in the part of the mechanoactivated material the bidentate bonding of the CH 3 COO - is transformed in monodentate one. The new-formed species is soluble in non-polar solvents.

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