Abstract
The solid-phase interaction of cobalt with boron during high-energy ball milling of Co80B20 and Co60B40 mixtures was studied. It was found that Co3B boride forms during the mechanical alloying of components in the presence of both modifications of Co with a reduction in the size of blocks of up to 7–15 nm. The transformation of the metastable Co3B phase into stable Co2B and CoB borides is observed in the temperature range of 590–700°C.
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