Abstract

A new luminogen PTZ-BZ-DBF bearing an electron donor phenothiazine unit and an electron acceptor carbonyl group is designed and synthesized. This molecule adopts highly twisted molecular conformation and exhibits intramolecular charge transfer (ICT), effective solid-state luminescence, and high contrast mechanofluorochromic (MFC) properties. The as-prepared powders show bright yellow-green fluorescence. Under conditions of external mechanical stimulation, the color changes to bright orange-red, and a red shift of 87 nm is observed in the emission spectral profile. Meanwhile, the solid-state luminescence efficiency increases from 20.5% to 28.5%. It is different from general MFC materials, when fumed using DCM vapor or annealed at 150 °C, the fluorescence peaks blue shift to approximately 560 nm, and the yellowish-emitting Y-powders are obtained. The ground solids and Y-powders can be converted to the as-prepared solid powders following the process of solvent recrystallization. Thus, tricolor switching is realized. The results obtained using the PXRD and DSC techniques indicate that the MFC phenomenon can be attributed to the process of crystalline-to-amorphous transition. The red shift of the PL spectra is attributed to the planar intramolecular charge transfer (PICT) process induced by conformational planarization in response to external forces.

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