Abstract
AbstractWith 1H and 31P NMR‐spectroscopy the solvation of Co(II)‐ions in mixtures of weak donors (methanol) and strong donors (dimethylformamide, hexamethylphosphoric acid triamide) was studied. In comparison with the complexes in the respective pure solvents, the ligand exchange rates of the strong donors are diminished and those of the weak donors are increased. These measurements yield information about the mechanism of the solvent exchange at metal ions and can be understood according to a donor‐acceptor model.
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