Mechanistic investigation of chemical looping combustion of coal with Fe 2O 3 oxygen carrier

Abstract

The reaction of three Chinese coals with Fe 2O 3 oxygen carrier (OC) was performed in a thermogravimetric analyzer (TGA), with special focuses on the effects of varying heating rate and coal rank on reactivity. Fourier transform infrared spectroscopy (FTIR) was used to in situ detect the emitted gases from TGA. Field scanning electron microscopy/energy-dispersive X-ray spectrometry (FSEM–EDX) was used to study the morphology and elemental compositions of the reaction residues collected from TGA and the related phase evaluation was further identified by X-ray diffraction (XRD). Through all these experiments, it was found that the pyrolysis of coal samples without Fe 2O 3 OC under N 2 atmosphere underwent the dehydration and the ensuing primary and secondary pyrolysis stages. The increasing heating rate shifted the characteristic temperature ( T m ) of the primary pyrolysis to a higher temperature and favored a more rapid generation of volatile matters. When the three coals reacting with Fe 2O 3 OC, TGA results demonstrated even over 200 °C, the reaction still experienced the partial pyrolysis at the relatively low temperature and the ensuing two reactions of Fe 2O 3 with the pyrolysis products at the primary and secondary stages. The coal of low rank with high volatile content should be preferred for the full conversion of coal into CO 2. Furthermore, the activation energy of Fe 2O 3 OC reacting with PDS at its primary pyrolysis stage was the largest, more than 70 kJ/mol. Finally, SEM–EDX and further XRD analysis of the residues from the reaction of PDS with Fe 2O 3 OC indicated the reduced counterpart of Fe 2O 3 was Fe 3O 4, and some inert iron compounds such as Fe 2SiO 4 and FeAl 2O 4 were also generated, which might deteriorate the reactivity of Fe 2O 3 OC.