Abstract

AbstractThe cover picture shows the catalytic cycle of the Pd‐catalysed asymmetric phosphination involving an achiral alkenyl triflate and a racemic boron phosphide. A mechanistic study illustrated by the gears in the background allowed us to identify each main intermediate of this catalytic cycle. To proceed, tools such as 31P NMR spectroscopy and X‐ray crystallography were used. Details are discussed in the article by A.‐C. Gaumont et al. on p. 2489 ff.

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