Mechanistic Insights into the Growth of Anisotropic Nanostructures Inside Reverse Micelles: A Solvation Perspective.

Abstract

Reverse micelles (RMs) as soft templates have been successfully used in tailoring the structural characteristics (size and morphology) of nanomaterials that in turn have been used in various applications. In this work, we have focused on the local perturbations in the different interior domains of the cetyltrimethylammonium bromide-reverse micelle-based soft template en route to nanorod formation by monitoring the solvation response of coumarin-based solvatochromic probes (C343 and C153). We have observed an appreciable retardation of the solvent coordinate during the initial phases of nanorod growth, which we have attributed to the reorientational motion of the water molecules lodged in the interfacial region. Moreover, these rigid nanostructures leave their imprints on the soft interfacial layer as was observed from the direct correlation in the solvation response of RM-containing nanostructures and respective surfactant aggregates in supernatant solution. Supporting data from time-resolved anisotropy studies further reinforced our conclusions from the solvation experiments. Our study proves that the hydration dynamics can be a promising tool in tracking the heterogeneous growth evolution of nanostructure formation in RMs since solvent reorganization provides insights into the intrinsic, molecular-level features of the micellar assemblies.