Mechanistic Insights into Hydrogen Activation by Frustrated N/Sn Lewis Pairs.

Abstract

The mechanism of H2 activation by recently reported N/Sn Lewis pairs is unravelled using the representative iPr3 SnOTf/DABCO combination. Computations provide evidence for weak intermolecular associations between Lewis acid and Lewis base (LA/LB) in which the counteranion to cationic LA fragment plays a critical role. Two frustrated Lewis pairs (FLPs) are observed; an unprecedented counteranion-mediated noncovalent LA/LB association is characterised along with the usual FLP structure. Both the FLPs are shown to be capable of H2 activation through cooperative electron transfer processes involving the LA/LB centres. Overall, computed results are in good agreement with the experimental findings and account for the observed reactivity. Insights obtained in this study are fundamentally important for the rational design of Sn-based alternative FLP LAs. The present findings could also provide a general mechanistic framework for H2 activation by FLPs having an ion pair LA component.